2-Ethylphenol (CAS 90-00-6) — Woody Base Note Fragrance Ingredient

Woody · Musky

2-Ethylphenol

CAS 90-00-6

Origin
synthetic
Note
Base
IFRA
Use with awareness
Data as of: Apr 2026

What Is 2-Ethylphenol?

2-Ethylphenol is a synthetic aromatic compound used in perfumery to add smoky, medicinal, or leathery notes. It’s found in trace amounts in some foods and beverages like whiskey and smoked meats. This ingredient matters because it provides depth and complexity to fragrances, especially those aiming for a rugged or vintage character.

Safety Profile

USE WITH AWARENESS
Generally safeUse with awarenessProfessional use
Potential skin irritant
Use in low concentrations
CAS
90-00-6
Formula
Mixture
MW
Variable
Odor Family
Woody · Musky
Layer 1 · Enthusiast

What Does 2-Ethylphenol Smell Like?

2-Ethylphenol delivers an intense, phenolic aroma with strong medicinal and smoky facets. Initial impressions are sharp and slightly rubbery, evolving into a leathery heart with hints of tobacco and burnt wood. The dry-down reveals a lingering, animalic warmth reminiscent of well-worn saddles or aged whiskey barrels.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Cuir de Russie(Chanel, 1924)

Used to enhance the leather accord, providing a smoky, slightly medicinal edge that complements the birch tar and floral notes.

Knize Ten(Knize, 1924)

Adds a rugged, vintage leather character to this classic masculine fragrance, balancing the floral and woody elements.

Layer 2

2D Molecular Structure

2-Ethylphenol

SMILES: CCC1=C(O)C=CC=C1

Chemistry, Properties & Perfumer Guide

The Chemistry

2-Ethylphenol is a simple phenol derivative with an ethyl group at the ortho position. It’s typically synthesized through alkylation of phenol or via microbial degradation of lignin. The compound’s aromaticity and hydroxyl group make it reactive in various chemical contexts, contributing to its distinctive odor profile.

Physical & Chemical Properties

Boiling Point198 °C
Density0.865 g/cm³

Perfumer Guide

Note Position
Base
Volatility
Medium (2-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Fine Fragrance0.1-0.5%Up to 1%Adds smoky leather accents
Leather Accord0.5-1%Up to 2%Enhances rugged character

Classic Accords

+ Birch Tar + Vanilla = Smoky Leather + Labdanum + Patchouli = Vintage Chypre

Tip: Use sparingly in leather accords to avoid overwhelming other notes.

Alternatives & Comparisons

1
Guaiacol CAS 90-05-1

When a smoother smoky note is desired, though less leathery than 2-ethylphenol.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

Not currently restricted by IFRA, but recommended for limited use due to potential sensitization.

GHS Classification

H315 Skin irritation H319 Eye irritation

RIFM Assessment

RIFM has assessed this material; use should be limited due to potential skin sensitization.

Sustainability

Typically produced synthetically from petrochemical sources. No significant environmental concerns at current usage levels, but alternatives may be preferred for green formulations.

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References

  1. PubChem: 2-Ethylphenol CID 6998

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 90-00-6

Physical Properties

Molecular Weight122.16 g/mol🔬 PubChem
LogP (Octanol-Water)2.5🔬 PubChem
Boiling Point204.5 °C🔬 EPA CompTox
Vapor Pressure1 mmHg @ 25°C📊 OPERA
Flash Point78.3 °C🔬 EPA CompTox
Involatility Index0.0975💻 Calculated
log Kp (skin permeability)-1.67💻 Calculated
SMILESCCC1=CC=CC=C1O🔬 PubChem

Volatility & Performance

Fragrance NoteTop💻 Calculated
Volatility ClassSlow💻 Calculated
Persistence Score0.5 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsphenolicsweet• leffingwell
Functional Groupsphenolaromatic💻 RDKit

Sensory Thresholds

Odor Detection Threshold0.3 ppm📖 van Gemert
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID1022479

Physical Properties

Molecular Weight 122.167 g/mol🔬 EPA CompTox
Density 1.027 g/cm^3🔬 EPA CTX
Boiling Point 202.824 °C🔬 EPA CTX
Melting Point -8.798 °C🔬 EPA CTX
Flash Point 79.72 °C🔬 EPA CTX
Refractive Index 1.537 Dimensionless📊 OPERA
Molar Volume 120.681 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 2.47 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) 2.529 Log10 unitless📊 OPERA
LogD (pH 7.4) 2.529 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 6.09 Log10 unitless📊 OPERA
Water Solubility 0.035 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole🔬 EPA CTX

Transport Properties

Vapor Pressure 0.154 mmHg🔬 EPA CTX
Viscosity 6.141 cP📊 OPERA
Surface Tension 36.881 dyn/cm📊 OPERA
Thermal Conductivity 147.089 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.23 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 1 count💻 Computed
Aromatic Rings 1 count💻 Computed
Molar Refractivity 37.684 cm^3/mol📊 OPERA
Polarizability 14.939 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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