Carbonic acid, 2-hydroxyethyl 5-methyl-2-(1-methylethyl)cyclohexyl ester (CAS 156679-39-9) — Green Middle Note Fragrance Ingredient
Carbonic acid, 2-hydroxyethyl 5-methyl-2-(1-methylethyl)cyclohexyl ester
CAS 156679-39-9
What Is Carbonic acid, 2-hydroxyethyl 5-methyl-2-(1-methylethyl)cyclohexyl ester?
This synthetic ingredient is a specialized ester used in niche perfumery. It appears in avant-garde fragrances seeking unusual woody-green effects. The molecule offers perfumers a unique bridge between fresh citrus top notes and deeper woody bases, creating novel scent transitions that defy traditional categories.
Safety Profile
GENERALLY SAFEWhat Does Carbonic acid, 2-hydroxyethyl 5-methyl-2-(1-methylethyl)cyclohexyl ester Smell Like?
Opens with a crisp, almost metallic greenness reminiscent of crushed stems, then unfolds into a complex woody heart with subtle citrus undertones. The dry-down reveals a faintly camphoraceous character that lingers close to the skin, like the memory of walking through a coniferous forest after rain.
Chemistry, Properties & Perfumer Guide
The Chemistry
This ester belongs to the cyclohexanol family, synthesized through esterification of menthol derivatives. Its unique structure creates both hydrophilic and lipophilic properties, allowing it to bridge aqueous and oil-based fragrance systems. The molecule’s stereochemistry significantly impacts its odor profile, with different enantiomers exhibiting distinct scent characteristics.
Physical & Chemical Properties
| Appearance | Colorless to pale yellow liquid |
|---|---|
| Molecular Weight | 228.32 g/mol |
Perfumer Guide
| Application | Typical % | Range | Notes |
|---|---|---|---|
| Conceptual Fragrances | 0.5-2% | Up to 5% | For avant-garde compositions |
| Functional Products | 0.1-0.5% | Up to 1% | Limited use due to cost |
Classic Accords
Tip: Use with citrus top notes to enhance freshness without being overly fruity.
Alternatives & Comparisons
Safety, Regulatory & Sustainability
⚠ Regulatory Disclaimer
General reference only. Consult current IFRA Standards Library before formulating.
IFRA Status
No current IFRA restrictions.
RIFM Assessment
Not currently assessed by RIFM.
Sustainability
Synthesized from petrochemical precursors, this material represents modern perfumery’s ability to create novel scent molecules. While not renewable, its high potency means minimal quantities are required in formulations. Future development could explore bio-based synthetic routes.
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References
- PubChem Compound Summary PubChem
Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.
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