Ethyl decanoate (CAS 110-38-3) — Sweet Middle/Top Note Fragrance Ingredient

Sweet · Citrus

Ethyl decanoate

CAS 110-38-3

Origin
synthetic
Note
Middle/Top
IFRA
Generally safe
Data as of: Apr 2026

What Is Ethyl decanoate?

Ethyl decanoate is a fruity ester commonly used in perfumes and food flavorings. You’ll encounter it in tropical fruit fragrances, apple flavors, and some alcoholic beverages. This versatile ingredient matters because it adds realistic, juicy fruitiness to scents without being overpowering. It’s a workhorse molecule that helps create convincing fruit accords from pineapple to pear.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
GRAS (Generally Recognized As Safe)
No known restrictions
CAS
110-38-3
Formula
Mixture
MW
Variable
Odor Family
Sweet · Citrus
Layer 1 · Enthusiast

What Does Ethyl decanoate Smell Like?

Ethyl decanoate bursts with a bright, waxy fruitiness reminiscent of overripe apples and pineapple cores. The initial impression is intensely sweet, like fruit leather drying in the sun, with a subtle fermented quality that adds complexity. As it dries, the waxy character becomes more pronounced, evoking beeswax candles dipped in pear nectar. The dry-down reveals a clean, almost soapy fruitiness that lingers softly without becoming cloying.

Scent Profile

In Famous Fragrances

Fragrance associations may not reflect actual formulations.

Eau des Merveilles(Hermès, 2004)

Provides the juicy, sun-warmed pear note that balances the ambergris and woods. Creates the illusion of fruit skins glistening with salt spray.

Light Blue(Dolce & Gabbana, 2001)

Used sparingly to enhance the crisp apple top note, adding a rounded, ripe quality that prevents the citrus from being too sharp.

Layer 2

2D Molecular Structure

Ethyl decanoate

SMILES: CCCCCCCCCC(=O)OCC

Chemistry, Properties & Perfumer Guide

The Chemistry

Ethyl decanoate belongs to the ester family, formed by the condensation of ethanol and decanoic acid. Industrially produced via Fischer esterification with acid catalysis, it’s a staple in both flavor and fragrance chemistry. The molecule’s ten-carbon chain gives it moderate volatility and excellent blending properties. Unlike shorter-chain esters, ethyl decanoate delivers fruity notes without excessive volatility or harshness.

Physical & Chemical Properties

Boiling Point243-245 °C
Density0.862 g/cm³
Flash Point>100 °C
Refractive Index1.423-1.427
SolubilityInsoluble in water, soluble in alcohol

Perfumer Guide

Note Position
Middle/Top
Volatility
Moderate (2-6 hours)
Blending
Excellent
ApplicationTypical %RangeNotes
Fine Fragrance0.5-3%Up to 5%Fruit accord modifier
Functional Fragrance0.1-1%Up to 2%Soap and detergent fruity notes
Flavor10-50 ppmUp to 100 ppmApple and pear flavors

Classic Accords

+ Aldehyde C-14 + Ethyl Maltol = Tropical Punch + Isoamyl Acetate + Hexyl Acetate = Apple Orchard + Gamma-Decalactone + Vanillin = Creamy Coconut

Tip: Use as a bridge between citrus top notes and lactonic base notes to create seamless fruit transitions.

Alternatives & Comparisons

1
Ethyl octanoate CAS 106-32-1

More volatile with sharper fruitiness, better for top notes when a quicker evaporation is desired.

2
Ethyl dodecanoate CAS 106-33-2

Longer-lasting with waxy character, used when more persistence is needed in the dry-down.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under IFRA standards.

RIFM Assessment

Evaluated by RIFM and found safe for current use levels in fragrance applications.

Sustainability

Synthetically produced from petrochemical feedstocks, ethyl decanoate has minimal environmental impact at current usage levels. Production is energy-efficient with high yields. No known issues with biodegradation or bioaccumulation.

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References

  1. Burdock, G.A. (2010). Fenaroli’s Handbook of Flavor Ingredients. CRC Press. ISBN 9781420090772

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Ingredient Data Sheet

CAS 110-38-3

Physical Properties

Molecular Weight200.32 g/mol🔬 PubChem
LogP (Octanol-Water)4.6🔬 PubChem
Boiling Point241 °C🔬 EPA CompTox
Vapor Pressure0.018 mmHg @ 25°C📊 OPERA
Flash Point218.5 °C🔬 EPA CompTox
Involatility Index0.0014💻 Calculated
log Kp (skin permeability)-0.656💻 Calculated
SMILESCCCCCCCCCC(=O)OCC🔬 PubChem

Volatility & Performance

Fragrance NoteHeart💻 Calculated
Volatility ClassVery slow💻 Calculated
Persistence Score4 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsfattynuttysweet• leffingwell
Functional Groupsesterether💻 RDKit
“probably one chemical that can recall the odor of the common Gardentulip flower best, out of all single chemicals.”📖 Arctander
Ethyl decanoate has a fruity odor reminiscent of grape (cognac). It has been also reported to have an oily, brandy-like odor.📖 Fenaroli

Flavor Notes (Arctander)

“Sweet, oily-nutlike odor with a rich, wine-yeast type background. Oily, "Brandy-rose"-like flavor. The subject material is widely used in flavor compositions, for imitation Arak, Rum, Brandy, Whisky, Cognac, and in Peach, Strawberry, Grape (white and green Grapes), Cherry, Pineapple, Plum, etc. as w”📖 Arctander

Sensory Thresholds

Odor Detection Threshold0.0082 ppm (n=7)📖 van Gemert

Regulatory Status

FEMA NumberFEMA 2432⚖️ FEMA GRAS
GRAS StatusGenerally Recognized as Safe⚖️ FEMA GRAS
IOFI ClassificationNature Identical📖 Fenaroli
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID0044363

Physical Properties

Molecular Weight 200.322 g/mol🔬 EPA CompTox
Density 0.866 g/cm^3🔬 EPA CTX
Boiling Point 243.167 °C🔬 EPA CTX
Melting Point -20 °C🔬 EPA CTX
Flash Point 131.15 °C🔬 EPA CTX
Refractive Index 1.43 Dimensionless📊 OPERA
Molar Volume 230.099 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 4.762 Log10 unitless📊 OPERA
LogD (pH 5.5) 4.762 Log10 unitless📊 OPERA
LogD (pH 7.4) 4.762 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 6.08 Log10 unitless📊 OPERA
Water Solubility 0 mol/L🔬 EPA CTX
Henry's Law Constant 0.001 atm-m3/mole🔬 EPA CTX

Transport Properties

Vapor Pressure 0.018 mmHg🔬 EPA CTX
Viscosity 2.501 cP📊 OPERA
Surface Tension 28.221 dyn/cm📊 OPERA
Thermal Conductivity 140.63 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 26.3 Ų💻 Computed
H-Bond Donors 0 count💻 Computed
H-Bond Acceptors 2 count💻 Computed
Rotatable Bonds 9 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 59.418 cm^3/mol📊 OPERA
Polarizability 23.555 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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