Heptyl alcohol (CAS 111-70-6) — Green Top to Middle Note Fragrance Ingredient

Green · Floral

Heptyl alcohol

CAS 111-70-6

Origin
synthetic
Note
Top to Middle
IFRA
Generally safe
Data as of: Apr 2026

What Is Heptyl alcohol?

Heptyl alcohol is a synthetic fragrance ingredient used to add fresh, green, and slightly floral notes to perfumes and household products. You’ll encounter it in laundry detergents, fabric softeners, and some citrus-based perfumes. This alcohol adds a crisp, clean character that helps balance sweeter or heavier ingredients in a fragrance composition.

Safety Profile

GENERALLY SAFE
Generally safeUse with awarenessProfessional use
Low toxicity profile
No known major restrictions
CAS
111-70-6
Formula
Mixture
MW
Variable
Odor Family
Green · Floral
Layer 1 · Enthusiast

What Does Heptyl alcohol Smell Like?

Heptyl alcohol presents a fresh, slightly waxy aroma with green undertones reminiscent of young leaves. Its initial sharpness quickly evolves into a cleaner, more floral character with subtle citrusy facets. The dry-down reveals a faintly soapy quality that makes it useful for functional fragrances, though it lacks the complexity to stand alone in fine perfumery.

Scent Profile
Layer 2

2D Molecular Structure

1-Heptanol

SMILES: CCCCCCCO

Chemistry, Properties & Perfumer Guide

The Chemistry

Heptyl alcohol (1-heptanol) is a straight-chain primary alcohol with seven carbon atoms. Industrially produced through hydroformylation of 1-hexene followed by hydrogenation, or via oxidation of heptane. As a medium-chain alcohol, it exhibits both hydrophilic and lipophilic properties, making it useful as a solvent and fragrance carrier. The molecule lacks chiral centers, existing as a single stereoisomer.

Physical & Chemical Properties

Boiling Point176 °C
Density0.822 g/cm³
Vapor Pressure0.5 mmHg at 25°C

Perfumer Guide

Note Position
Top to Middle
Volatility
Medium (1-4 hours)
Blending
Good
ApplicationTypical %RangeNotes
Functional Fragrances1-5%Up to 10%Adds freshness to cleaning products
Fine Fragrance0.5-2%Up to 5%Used as modifier in citrus/floral accords

Classic Accords

Tip: Use to brighten heavy floral bases without adding excessive sweetness.

Alternatives & Comparisons

1
Hexyl alcohol CAS 111-27-3

Shorter carbon chain provides sharper green notes with less waxy character.

2
Octyl alcohol CAS 111-87-5

Longer chain creates more floral, less green profile with better persistence.

Layer 3

Safety, Regulatory & Sustainability

⚠ Regulatory Disclaimer

General reference only. Consult current IFRA Standards Library before formulating.

IFRA Status

No restrictions under current IFRA standards.

GHS Classification

H315 Skin irritation H319 Eye irritation

RIFM Assessment

Considered safe for current fragrance uses based on RIFM assessments.

Sustainability

Synthesized from petrochemical feedstocks, though production routes are energy-efficient. No known ecological accumulation concerns due to ready biodegradability. Not currently available from renewable sources at commercial scale.

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References

  1. PubChem Compound Summary for CID 8129 PubChem CID 8129

Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.

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Perfumer’s Notes

FEMA #: 2548  |  IOFI #: Nature Identical

Heptyl alcohol has a fragrant, woody, heavy, oily, faint, aromatic, fatty odor and a pungent, spicy taste.

Odor: [‘fatty’, ‘fresh’, ‘green’]

MW: 116.20

LogP: 2.7

Ingredient Data Sheet

CAS 111-70-6

Physical Properties

Molecular Weight116.2 g/mol🔬 PubChem
LogP (Octanol-Water)2.7🔬 PubChem
Boiling Point176.1 °C🔬 EPA CompTox
Vapor Pressure0.21 mmHg @ 25°C📊 OPERA
Flash Point76.7 °C🔬 EPA CompTox
Involatility Index0.021💻 Calculated
log Kp (skin permeability)-1.492💻 Calculated
SMILESCCCCCCCO🔬 PubChem

Volatility & Performance

Fragrance NoteTop💻 Calculated
Volatility ClassSlow💻 Calculated
Persistence Score1 / 5💻 Calculated

Odor & Flavor

Primary Descriptorsfattyfreshgreen• leffingwell
Functional Groupsalcohol💻 RDKit
“Fresh and light, green-fatty, winy and sap-like odor of poor tenacity.”📖 Arctander
Heptyl alcohol has a fragrant, woody, heavy, oily, faint, aromatic, fatty odor and a pungent, spicy taste.📖 Fenaroli

Flavor Notes (Arctander)

“Sweet winy-nut-like taste. Green only in high concentration. It is also used in flavor compositions for imitation Coconut, and in various fruit complexes.”📖 Arctander

Sensory Thresholds

Odor Detection Threshold0.8471 ppm (n=14)📖 van Gemert

Regulatory Status

FEMA NumberFEMA 2548⚖️ FEMA GRAS
GRAS StatusGenerally Recognized as Safe⚖️ FEMA GRAS
IOFI ClassificationNature Identical📖 Fenaroli
Data Sources & Attribution
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.

Physicochemical Properties

DTXSID: DTXSID8021937

Physical Properties

Molecular Weight 116.204 g/mol🔬 EPA CompTox
Density 0.822 g/cm^3🔬 EPA CTX
Boiling Point 177.503 °C🔬 EPA CTX
Melting Point -31.325 °C🔬 EPA CTX
Flash Point 72.975 °C🔬 EPA CTX
Refractive Index 1.422 Dimensionless📊 OPERA
Molar Volume 141.589 cm^3/mol📊 OPERA

Partition & Solubility

LogP (Octanol-Water) 2.606 Log10 unitless🔬 EPA CTX
LogD (pH 5.5) 2.681 Log10 unitless📊 OPERA
LogD (pH 7.4) 2.681 Log10 unitless📊 OPERA
LogKoa (Octanol-Air) 4.97 Log10 unitless📊 OPERA
Water Solubility 0.015 mol/L🔬 EPA CTX
Henry's Law Constant 0 atm-m3/mole🔬 EPA CTX

Transport Properties

Vapor Pressure 0.308 mmHg🔬 EPA CTX
Viscosity 4.169 cP📊 OPERA
Surface Tension 27.282 dyn/cm📊 OPERA
Thermal Conductivity 149.819 mW/(m*K)📊 OPERA

Molecular Descriptors

Topological Polar Surface Area 20.23 Ų💻 Computed
H-Bond Donors 1 count💻 Computed
H-Bond Acceptors 1 count💻 Computed
Rotatable Bonds 5 count💻 Computed
Aromatic Rings 0 count💻 Computed
Molar Refractivity 36.014 cm^3/mol📊 OPERA
Polarizability 14.277 Å^3📊 OPERA

Data Sources:

🔬 EPA Experimental data from U.S. EPA CompTox Chemicals Dashboard & CTX APIs. 📊 OPERA Predicted using EPA's OPERA QSAR models. 💻 Computed Calculated from SMILES using RDKit.

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