trans-Cinnamic acid (CAS 0140-10-3) — Sweet Middle Note Fragrance Ingredient
trans-Cinnamic acid
CAS 0140-10-3
What Is trans-Cinnamic acid?
trans-Cinnamic acid is a naturally occurring organic compound found in cinnamon and other plants. It’s used in perfumery for its sweet, balsamic aroma. This ingredient matters because it bridges the gap between floral and spicy notes, adding warmth and complexity to fragrances while being biodegradable.
Safety Profile
GENERALLY SAFEWhat Does trans-Cinnamic acid Smell Like?
trans-Cinnamic acid opens with a bright, honeyed sweetness reminiscent of dried apricots, quickly revealing a resinous core like crushed pine needles in sunlight. As it dries, it develops a velvety vanilla-cinnamon character that lingers close to the skin, creating an intimate sillage. The evolution mirrors melting amber – starting sharp and crystalline, then softening into a warm, woody embrace.
In Famous Fragrances
Fragrance associations may not reflect actual formulations.
Chemistry, Properties & Perfumer Guide
The Chemistry
An unsaturated carboxylic acid with the phenyl group adjacent to the acrylic acid moiety. Naturally occurs as both trans- and cis- isomers, with the trans- form being more stable and prevalent. Synthetically produced via Perkin reaction between benzaldehyde and acetic anhydride. The conjugated π-system contributes to its UV absorption and fluorescence properties.
Physical & Chemical Properties
| Melting Point | 133 °C |
|---|---|
| Boiling Point | 300 °C |
| Solubility | Slightly in water, soluble in organic solvents |
Perfumer Guide
| Application | Typical % | Range | Notes |
|---|---|---|---|
| Fine Fragrance | 1-3% | Up to 5% | Adds warmth to oriental bases |
| Functional Fragrance | 0.5-1% | Up to 2% | Masking agent for household products |
Classic Accords
Tip: Use ethanol as solvent to prevent crystallization in final products.
Alternatives & Comparisons
More intense cinnamon character but higher sensitization potential. Used when stronger spice impact is needed.
Safety, Regulatory & Sustainability
⚠ Regulatory Disclaimer
General reference only. Consult current IFRA Standards Library before formulating.
IFRA Status
Not currently restricted by IFRA. Listed as safe at current usage levels in fine fragrances.
GHS Classification
RIFM Assessment
RIFM assessment confirms safe use up to 3.8% in leave-on products.
Sustainability
Can be sourced sustainably from cinnamon bark waste streams. Synthetic production avoids agricultural impacts but requires petrochemical feedstocks. Biodegradation occurs within 28 days under OECD test conditions.
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References
- PubChem Compound Summary for trans-Cinnamic acid CID 637542
Data: PubChem (NIH), PubMed, RIFM, IFRA. Last reviewed: Apr 2026.
Report a data errorIngredient Data Sheet
CAS 0140-10-3Physical Properties
| Molecular Weight | 148.16 g/mol🔬 PubChem |
| LogP (Octanol-Water) | 2.1🔬 PubChem |
| log Kp (skin permeability) | -2.113💻 Calculated |
Odor & Flavor
| Primary Descriptors | floralhoney• leffingwell |
Sensory Thresholds
| Odor Detection Threshold | 3.1623 ppm (n=2)📖 van Gemert |
Physical data: PubChem (NIH/NLM), U.S. EPA CompTox Dashboard, EPA OPERA models, RDKit. Odor & flavor: Arctander (Perfume & Flavor Chemicals), Fenaroli's Handbook of Flavor Ingredients, Leffingwell. Thresholds: van Gemert (Compilations of Odour Threshold Values). Regulatory: IFRA Standards 51st, FEMA GRAS. Trade names: Surburg (Common Fragrance & Flavor Materials). All data compiled and cross-referenced for perfumertools.com.
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